Fuzzy Nanoparticles: New Way to Design Tougher Ballistic Materials

This phenomenon was useful for the material’s initial purpose, which was permitting gases to move through it quickly. But Chan and others at NIST sought to find out how this unique property would affect toughness. With the help of Kumar’s lab, the researchers tested samples of varying molecular masses. 

“We grew polymeric hair off of the particles from a really short, brush-cut regime to a very long, hippie regime,” said NIST materials research engineer and co-author Chris Soles. “The brush-cut nanoparticles don’t entangle and can pack together, but as the polymers get longer, the distance between nanoparticles expands and the chains between particles start to entangle and form a network.”

At NIST, the researchers opened fire on the PGN composite films of different molecular masses with a technique known as Laser-Induced Projectile Impact Testing, or LIPIT. These high-velocity impact tests involved propelling 10-micrometer-wide (about four-thousandths of an inch) spherical projectiles toward the targets at velocities of nearly 1 kilometer per second (more than 2,200 miles per hour) with a laser. 

They determined the velocity of the projectile in transit and on impact through images captured with a camera and strobe light flashing every 100 nanoseconds (billionths of a second). From there, the team had what it needed to calculate the energy it took to tear through the film, a quantity directly tied to toughness. 

The authors of the study found that the PGN composite films were generally tougher than solely PMA. But what was perhaps more interesting was that intermediate molecular mass yielded the toughest film.

In purely polymeric materials, longer chains tend to create a greater number of tangles. And more tangles translate to greater toughness, up to the point where the material is completely tied up. However, the LIPIT tests revealed that the films could defy traditional polymer behavior. The toughest samples had chains far shorter than the length for full entanglement, meaning that tangles were not the only factor driving toughness. 

Soles and his colleagues suspected that the reason was the decreased packing between the chains at the intermediate molecular masses, which could have created a situation where polymers could wriggle about more freely and create friction with neighboring chains — a potential avenue for dissipating energy from a high impact. 

Seeking to pin down the underlying source of the toughness and test their hypothesis, the team members used equipment at the NIST Center for Neutron Research to assess the motion of the polymers. 

These tests confirmed that the intermediate molecular mass chains attached to the nanoparticles displayed an ability to move and then reach a relaxed state in just a few picoseconds (trillionths of a second). These enhanced movements of the intermediate chains dissipated energy more readily than either the short (no tangles) or long (highly entangled) PMA chains. This finding backed the team’s intuition, especially when taken along with the LIPIT tests.  

“Right at that molecular mass where the PGN composite films showed the highest impact resistance, the grafted PMA chains showed the highest mobility and energy dissipation,” Soles said. 

The results of this study hint at the existence of a sweet spot with respect to the length of polymers fixed to the curved surface of particles that could boost material toughness. The finding may not be limited to PMA either.

“Based on this kind of platform, the grafted nanoparticle concept, you can start experimenting with more classic high-impact polymers such as the polycarbonates used in bulletproof windows,” Chan said. “There’s just so much to explore. We’re only just scratching the surface of these materials.”