WaterGetting the salt out

By David L. Chandler

Published 22 October 2014

The boom in oil and gas produced through hydraulic fracturing, or fracking, is seen as a boon for meeting U.S. energy needs. But one byproduct of the process is millions of gallons of water that’s much saltier than seawater, after leaching salts from rocks deep below the surface. Study shows electrodialysis can provide cost-effective treatment of salty water from fracked wells.

The boom in oil and gas produced through hydraulic fracturing, or fracking, is seen as a boon for meeting U.S. energy needs. But one byproduct of the process is millions of gallons of water that’s much saltier than seawater, after leaching salts from rocks deep below the surface.

Now researchers at MIT and in Saudi Arabia say they have found an economical solution for removing the salt from this water. The new analysis appears in the journal Applied Energy, in a paper co-authored by MIT professor John Lienhard, postdoc Ronan McGovern, and four others.

The method they propose for treating the “produced water” that flows from oil and gas wells throughout their operation is one that has been known for decades, but had not been considered a viable candidate for extremely high-salinity water, such as that produced from oil and gas wells. The technology, electrodialysis, “has been around for at least 50 years,” says Lienhard, the Abdul Latif Jameel Professor of Water and Food as well as director of the Center for Clean Water and Clean Energy at MIT and King Fahd University of Petroleum and Minerals (KFUPM).

The research team also included graduate student Adam Weiner, graduate student Lige Sun, and undergraduate Chester Chambers at MIT, and Professor Syed Zubair at KFUPM.

“Electrodialysis is generally thought of as being advantageous for relatively low-salinity water,” Lienhard says — such as the brackish, shallow groundwater found in many locations, generally with salinity around one-tenth that of seawater. But electrodialysis also turns out to be economically viable at the other end of the salinity spectrum, the new analysis shows.

Extra salty
Produced water from fossil-fuel wells can have salinity three to six times greater than that of seawater; the new research indicates that this salt can be effectively removed through a succession of stages of electrodialysis.

The idea would not be to purify the water sufficiently to make it potable, the researchers say. Rather, it could be cleaned up enough to enable its reuse as part of the hydraulic fracturing fluid injected in subsequent wells, significantly reducing the water needed from other sources.

Lienhard explains that if you’re trying to make pure water, electrodialysis becomes less and less efficient as the water gets less saline, because it requires that electric current flow through the water itself: Salty water conducts electricity well, but pure water does not.