A New Way to Assess Radiation Damage in Reactors

Short and Al Dajani embarked on the process in 2018, looking for a more rapid way to detect a specific kind of degradation, called spinodal decomposition, that can take place in austenitic stainless steel, which is used for components such as the 2- to 3-foot wide pipes that carry coolant water to and from the reactor core. This process can lead to embrittlement, cracking, and potential failure in the event of an emergency.

While spinodal decomposition is not the only type of degradation that can occur in reactor components, it is a primary concern for the lifetime and sustainability of nuclear reactors, Short says.

“We were looking for a signal that can link material embrittlement with properties we can measure, that can be used to estimate lifetimes of structural materials,” Al Dajani says.

They decided to try a technique Short and his students and collaborators had expanded upon, called transient grating spectroscopy, or TGS, on samples of reactor materials known to have experienced spinodal decomposition as a result of their reactor-like thermal aging history. The method uses laser beams to stimulate, and then measure, SAWs on a material. The idea was that the decomposition should slow down the rate of heat flow through the material, that slowdown would be detectable by the TGS method.

However, it turns out there was no such slowdown. “We went in with a hypothesis about what we would see, and we were wrong,” Short says.

That’s often the way things work out in science, he says. “You go in guns blazing, looking for a certain thing, for a great reason, and you turn out to be wrong. But if you look carefully, you find other patterns in the data that reveal what nature actually has to say.”

Instead, what showed up in the data was that, while a material would usually produce a single frequency peak for the material’s SAWs, in the degraded samples there was a splitting into two peaks.

“It was a very clear pattern in the data,” Short recalls. “We just didn’t expect it, but it was right there screaming at us in the measurements.”

Cast austenitic stainless steels like those used in reactor components are what’s known as duplex steels, actually a mixture of two different crystal structures in the same material by design. But while one of the two types is quite impervious to spinodal decomposition, the other is quite vulnerable to it. When the material starts to degrade, the difference shows up in the different frequency responses of the material, which is what the team found in their data.

That finding was a total surprise, though. “Some of my current and former students didn’t believe it was happening,” Short says. “We were unable to convince our own team this was happening, with the initial statistics we had.” So, they went back and carried out further tests, which continued to strengthen the significance of the results. They reached a point where the confidence level was 99.9 percent that spinodal decomposition was indeed coincident with the wave peak separation.

“Our discussions with those who opposed our initial hypotheses ended up taking our work to the next level,” Al Dajani says.

The tests they did used large lab-based lasers and optical systems, so the next step, which the researchers are hard at work on, is miniaturizing the whole system into something that can be an easily portable test kit to use to check reactor components on-site, reducing the length of shutdowns. “We’re making great strides, but we still have some way to go,” he says.

But when they achieve that next step, he says, it could make a significant difference. “Every day that your nuclear plant goes down, for a typical gigawatt-scale reactor, you lose about $2 million a day in lost electricity,” Al Dajani says, “so shortening outages is a huge thing in the industry right now.”

He adds that the team’s goal was to find ways to enable existing plants to operate longer: “Let them be down for less time and be as safe or safer than they are right now — not cutting corners, but using smart science to get us the same information with far less effort.” And that’s what this new technique seems to offer.

Short hopes that this could help to enable the extension of power plant operating licenses for some additional decades without compromising safety, by enabling frequent, simple and inexpensive testing of the key components. Existing, large-scale plants “generate just shy of a billion dollars in carbon-free electricity per plant each year,” he says, whereas bringing a new plant online can take more than a decade. “To bridge that gap, keeping our current nukes online is the single biggest thing we can do to fight climate change.”

David L. Chandler writes about energy, engineering, and materials science for the MIT News Office. The article  is reprinted with permission of MIT News.