Nuclear mattersHistoric sample of bomb-grade plutonium discovered

Many smart people pointed to the relationship between past and future. Thus, Joseph Stalin said that “He who controls the past, controls the future,” and George Santayana said that “Those who ignore the past are doomed to repeat it.” Every once in a while, we, too, look back. A few weeks ago (22 January HS Daily Wire) we wrote about how the oldest batch of weapons-grade plutonium was found inside a glass jar buried at a dump at the Hanford nuclear reservation in Washington State. In this month’s issue of ACS’ Analytical Chemistry, Erika Gebel adds to the story by noting that the research which led to the discovery also represents the first demonstration of how radioactive sodium can be used as a tool in nuclear forensics.

In the new study, Jon Schwantes and colleagues note increased concern about the possibility of terrorists smuggling radioactive materials to make illegal nuclear weapons. As a result, scientists are stepping up efforts to identify and track the source of these radioactive materials using the advanced tools and techniques of a new field called “nuclear archeology.” The scientists describe efforts to determine the origin of an unknown sample of plutonium (Pu) found in 2004 in a bottle at a waste burial trench at the Hanford nuclear site in Washington. Hanford is the earliest location for U.S. plutonium production for nuclear weapons and now the focus of a massive environmental cleanup effort due to high levels of radioactive waste that remain at the site.

Using multiple pairs of “parent” Pu and “daughter” uranium (U) isotopes, the researchers were able to correct for chemical fractionation that occurred as a result of repackaging in 2004 and determine the age of the sample. Using this technique, they estimated that the Pu in the sample had been separated from U and fission products in 1944, making it the oldest known sample of bomb-grade plutonium produced in a reactor. The only older known samples of Pu-239 were produced by the late Glenn Seaborg and his associates in the beginning of the 1940s when the existence of the element was first confirmed and characterized.

The study identified the Clinton reactor in Oak Ridge, Tennessee, as reactor of origin for this material, by comparing reactor burnup modeling results with measurements of minor Pu isotopes. These results were also supported by a series of historical documents tracking the material’s movement from Oak Ridge and the processing at Hanford. “Aside from the historical significance of this find, this work provides the public a rare glimpse at a real-world example of the science behind and power of modern-day nuclear forensics,” the scientists note.

-read more in Erika Gebel, “Old Plutonium, New Tricks,” Analytical Chemistry 81, no. 5 (2009); and Jon M. Schwantes et al., “Nuclear Archeology in a Bottle: Evidence of Pre-Trinity U.S. Weapons Activities from a Waste Burial Site,” Analytical Chemistry (16 January 2009), (DOI: 10.1021/ac802286a)